Corey-Chaykovsky reaction of chiral sulfinyl imines: A convenient procedure for the formation of chiral aziridines

Morton, Daniel, Pearson, David, Field, Robert A. ORCID: https://orcid.org/0000-0001-8574-0275 and Stockman, Robert A. (2003) Corey-Chaykovsky reaction of chiral sulfinyl imines: A convenient procedure for the formation of chiral aziridines. Synlett (13). pp. 1985-1988. ISSN 0936-5214

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Abstract

The reaction of dimethylsulfonium methylide with a range of aromatic, heterocyclic and aliphatic tert-butylsulfinyl imines is presented. Aziridines were formed in 63-84% yield and 77-95% diastereomeric excess.

Item Type: Article
Uncontrolled Keywords: aziridine,corey-chaykovsky,imine,sulfinyl imine,ylide,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1605
Faculty \ School: Faculty of Science > School of Chemical Sciences and Pharmacy (former - to 2009)
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Depositing User: LivePure Connector
Date Deposited: 10 Sep 2024 12:30
Last Modified: 25 Sep 2024 18:08
URI: https://ueaeprints.uea.ac.uk/id/eprint/96654
DOI: 10.1055/s-2003-42028

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