Synthesis of triazole-linked pseudo-starch fragments

Nepogodiev, Sergey A., Dedola, Simone, Marmuse, Laurence, de Oliveira, Marcelo T. and Field, Robert A. ORCID: https://orcid.org/0000-0001-8574-0275 (2007) Synthesis of triazole-linked pseudo-starch fragments. Carbohydrate Research, 342 (3-4). pp. 529-540. ISSN 0008-6215

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Abstract

Rapid assembly of starch fragment analogues was achieved using 'click chemistry'. Specifically, a pentadecasaccharide and two hexadecasaccharide mimics containing two parallel maltoheptaosyl chains linked via [1,2,3]-triazoles to glucose or maltose core were synthesised using Cu(I)-catalyzed [3+2] dipolar cycloaddition of azidosaccharides and 4,6-di-O-propargylated methyl α-d-glucopyranoside and 6,6′- and 4′,6′-di-O-propargylated p-methoxyphenyl β-maltoside.

Item Type:	Article
Additional Information:	Funding Information: We are grateful to the EPSRC and the Weston Foundation for financial support and we are indebted to the EPSRC Mass Spectrometry Service Centre, Swansea, for invaluable support.
Uncontrolled Keywords:	amylopectin mimics,dipolar cycloaddition,analytical chemistry,biochemistry,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1602
Faculty \ School:	Faculty of Science > School of Chemical Sciences and Pharmacy (former - to 2009)
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	06 Sep 2024 13:35
Last Modified:	25 Sep 2024 18:07
URI:	https://ueaeprints.uea.ac.uk/id/eprint/96614
DOI:	10.1016/j.carres.2006.09.026

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