Prior, Christopher, Webster, Lee R., Ibrahim, Saad K., Wright, Joseph A. ORCID: https://orcid.org/0000-0001-9603-1001, Alghamdi, Ali F., Oganesyan, Vasily S.
ORCID: https://orcid.org/0000-0002-8738-1146 and Pickett, Christopher J.
(2016)
EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution.
Dalton Transactions, 45 (6).
pp. 2399-2403.
ISSN 1477-9226
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Abstract
EPR spectroscopy and theoretical data show that the slow heterogeneous electron-transfer kinetics associated with the reduction of an 18-electron Mo(IV) acetato dihydride are a consequence of an η2−η1 rearrangement of the carboxylate ligand which gives a unique paramagnetic 17-electron Mo(III) dihydride.
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