EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution

Prior, Christopher, Webster, Lee R., Ibrahim, Saad K., Wright, Joseph A. ORCID: https://orcid.org/0000-0001-9603-1001, Alghamdi, Ali F., Oganesyan, Vasily S. ORCID: https://orcid.org/0000-0002-8738-1146 and Pickett, Christopher J. (2016) EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution. Dalton Transactions, 45 (6). pp. 2399-2403. ISSN 1477-9226

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Abstract

EPR spectroscopy and theoretical data show that the slow heterogeneous electron-transfer kinetics associated with the reduction of an 18-electron Mo(IV) acetato dihydride are a consequence of an η2−η1 rearrangement of the carboxylate ligand which gives a unique paramagnetic 17-electron Mo(III) dihydride.

Item Type: Article
Additional Information: A correction for this article has been published relating to the author affiliations: https://doi.org/10.1039/C6DT90066F
Faculty \ School: Faculty of Science > School of Chemistry
Faculty of Science
Depositing User: Pure Connector
Date Deposited: 18 Jan 2016 15:00
Last Modified: 09 Aug 2022 16:33
URI: https://ueaeprints.uea.ac.uk/id/eprint/56365
DOI: 10.1039/C5DT04432D

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