EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution

Prior, Christopher, Webster, Lee R., Ibrahim, Saad K., Wright, Joseph A., Alghamdi, Ali F., Oganesyan, Vasily S. and Pickett, Christopher J. (2016) EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution. Dalton Transactions, 45 (6). pp. 2399-2403. ISSN 1477-9226

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Abstract

EPR spectroscopy and theoretical data show that the slow heterogeneous electron-transfer kinetics associated with the reduction of an 18-electron Mo(IV) acetato dihydride are a consequence of an η2−η1 rearrangement of the carboxylate ligand which gives a unique paramagnetic 17-electron Mo(III) dihydride.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Faculty of Science
Depositing User: Pure Connector
Date Deposited: 18 Jan 2016 15:00
Last Modified: 24 Jun 2020 23:57
URI: https://ueaeprints.uea.ac.uk/id/eprint/56365
DOI: 10.1039/C5DT04432D

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