EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution

Prior, Christopher, Webster, Lee R., Ibrahim, Saad K., Wright, Joseph A., Alghamdi, Ali F., Oganesyan, Vasily S. and Pickett, Christopher J. (2016) EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution. Dalton Transactions, 45 (6). pp. 2399-2403. ISSN 1477-9226

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Abstract

EPR spectroscopy and theoretical data show that the slow heterogeneous electron-transfer kinetics associated with the reduction of an 18-electron Mo(IV) acetato dihydride are a consequence of an η2−η1 rearrangement of the carboxylate ligand which gives a unique paramagnetic 17-electron Mo(III) dihydride.

Item Type:	Article
Additional Information:	A correction for this article has been published relating to the author affiliations: https://doi.org/10.1039/C6DT90066F
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024) Faculty of Science
UEA Research Groups:	Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Life Processes Faculty of Science > Research Centres > Centre for Molecular and Structural Biochemistry Faculty of Science > Research Groups > Energy Materials Laboratory Faculty of Science > Research Groups > Centre for Photonics and Quantum Science
Depositing User:	Pure Connector
Date Deposited:	18 Jan 2016 15:00
Last Modified:	15 Jul 2025 23:49
URI:	https://ueaeprints.uea.ac.uk/id/eprint/56365
DOI:	10.1039/C5DT04432D

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