EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution

Prior, Christopher, Webster, Lee R., Ibrahim, Saad K., Wright, Joseph A. ORCID: https://orcid.org/0000-0001-9603-1001, Alghamdi, Ali F., Oganesyan, Vasily S. ORCID: https://orcid.org/0000-0002-8738-1146 and Pickett, Christopher J. (2016) EPR detection and characterisation of a paramagnetic Mo(III) dihydride intermediate involved in electrocatalytic hydrogen evolution. Dalton Transactions, 45 (6). pp. 2399-2403. ISSN 1477-9226

Preview

PDF (C5DT04432D) - Accepted Version Download (807kB) | Preview

Abstract

EPR spectroscopy and theoretical data show that the slow heterogeneous electron-transfer kinetics associated with the reduction of an 18-electron Mo(IV) acetato dihydride are a consequence of an η2−η1 rearrangement of the carboxylate ligand which gives a unique paramagnetic 17-electron Mo(III) dihydride.

Item Type:	Article
Additional Information:	A correction for this article has been published relating to the author affiliations: https://doi.org/10.1039/C6DT90066F
Faculty \ School:	Faculty of Science > School of Chemistry Faculty of Science
UEA Research Groups:	Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Life Processes Faculty of Science > Research Centres > Centre for Molecular and Structural Biochemistry Faculty of Science > Research Groups > Energy Materials Laboratory Faculty of Science > Research Groups > Centre for Photonics and Quantum Science
Depositing User:	Pure Connector
Date Deposited:	18 Jan 2016 15:00
Last Modified:	15 Dec 2023 01:46
URI:	https://ueaeprints.uea.ac.uk/id/eprint/56365
DOI:	10.1039/C5DT04432D

Downloads

Actions (login required)

View Item