The kinetics of propene and hexene polymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states

Song, Fuquan, Cannon, Roderick D. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2004) The kinetics of propene and hexene polymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states. Chemical Communications (5). pp. 542-543. ISSN 1359-7345

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Abstract

Whereas the rates of propene polymerisation catalysed by zirconocene ion pairs are strongly anion-dependent, hexene polymerisations are not; the findings demonstrate the existence of very different kinetic regimes for two closely related reactions.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemical Sciences and Pharmacy (former - to 2009) Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	06 Mar 2023 15:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10499
DOI:	10.1039/b314845a

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