Laser-induced fluorescence from CuCl2 in a free-jet expansion: High-resolution fourier transform spectra

Ross, A. J., Crozet, P., Bacis, R., Churassy, S., Erba, B., Ashworth, S. H., Lakin, N. M., Wickham, M. R., Beattie, I. R. and Brown, J. M. (1996) Laser-induced fluorescence from CuCl2 in a free-jet expansion: High-resolution fourier transform spectra. Journal of Molecular Spectroscopy, 177 (1). pp. 134-142. ISSN 0022-2852

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Abstract

High-resolution Fourier transform spectra of the laser-induced fluorescence of copper dichloride produced in a free-jet expansion are presented. The supersonic molecular beam produces rotational cooling and a nearly collision-free environment. Dispersed fluorescence spectra are found to be free of the continuum which restricted the data obtainable with a classical source (hot cell). The reduction in thermal emission allows the fluorescence to be recorded from the laser line (585 nm) out to 1.3 μm, revealing many new vibrational levels of CuCl2 in its ground electronic state, X̃ 2Πg(3/2).

Item Type:	Article
Uncontrolled Keywords:	atomic and molecular physics, and optics,spectroscopy,physical and theoretical chemistry ,/dk/atira/pure/subjectarea/asjc/3100/3107
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	26 Jun 2025 09:30
Last Modified:	26 Jun 2025 09:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/99735
DOI:	10.1006/jmsp.1996.0125

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