Iodine: A versatile reagent in carbohydrate chemistry III. Efficient activation of glycosyl halides in combination with DDQ1

Kartha, K. P.Ravindranathan, Aloui, Mahmoud and Field, Robert A. ORCID: https://orcid.org/0000-0001-8574-0275 (1996) Iodine: A versatile reagent in carbohydrate chemistry III. Efficient activation of glycosyl halides in combination with DDQ1. Tetrahedron Letters, 37 (48). pp. 8807-8810. ISSN 0040-4039

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Abstract

Iodine, either alone or in combination with DDQ, has been found to serve as a very efficient reagent for the conversion of 'disarmed' glycosyl halides into simple 1,2-trans-glycosides. This reagent system represents a practical alternative to traditional heavy metal promoters in glycoside synthesis.

Item Type:	Article
Additional Information:	Funding Information: Acknowledgements: We thank the Wellcome Trust, the BBSRC / EPSRC and the Zeneca Strategic Research Fund for financial support. Bruce Turnbull and Shona Smith are thanked for assisting with the gram scale experiments.
Uncontrolled Keywords:	biochemistry,drug discovery,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1300/1303
Faculty \ School:	Faculty of Science > School of Chemistry, Pharmacy and Pharmacology
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	11 Sep 2024 14:30
Last Modified:	25 Sep 2024 18:09
URI:	https://ueaeprints.uea.ac.uk/id/eprint/96712
DOI:	10.1016/S0040-4039(96)01995-8

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