Observations on iodine-promoted β-mannosylation

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Marsh, Steven J., Kartha, K. P. Ravindranathan and Field, Robert A. ORCID: https://orcid.org/0000-0001-8574-0275 (2003) Observations on iodine-promoted β-mannosylation. Synlett (9 SPEC. ISS.). pp. 1376-1378. ISSN 0936-5214

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Abstract

The stereoselectivity of iodine-promoted glycosylation with mannosyl sulfoxides gives rise to unexpected β-selectivity with less reactive alcohol acceptors. Less reactive accceptors also give better coupling yields. Comparison of iodine with other promoters highlights differences in reaction rates and stereoselectivities indicative of different reaction mechanisms.

Item Type:	Article
Uncontrolled Keywords:	carbohydrates,glycosylations,iodine,stereoselectivity,sulfoxides,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1605
Faculty \ School:	Faculty of Science > School of Chemistry, Pharmacy and Pharmacology
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	10 Sep 2024 12:30
Last Modified:	25 Sep 2024 18:08
URI:	https://ueaeprints.uea.ac.uk/id/eprint/96656
DOI:	10.1055/s-2003-40346

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