"Click chemistry" en route to pseudo-starch

Tools

Marmuse, Laurence, Nepogodiev, Sergey A. and Field, Robert A. ORCID: https://orcid.org/0000-0001-8574-0275 (2005) "Click chemistry" en route to pseudo-starch. Organic and Biomolecular Chemistry, 3 (12). pp. 2225-2227. ISSN 1477-0520

Full text not available from this repository. (Request a copy)

Abstract

The application of click chemistry based on cycloaddition of substituted azide and alkynes to the synthesis of well-defined branched oligosaccharide related to starch was discussed. This modular approach allowed the construction of a number of [1,2,3]-triazole based analogues of amylopectin fragments in one simple coupling step. These analogues include two isomeric hexadecasaccharide analogues which have the potential for templating formation of double helixes between two parallel maltoheptaosyl chains attached to a core maltose unit. The results show that isomeric di-O-propargyl derivatives were synthesized starting from readily available maltose peracetate.

Item Type:	Article
Uncontrolled Keywords:	biochemistry,physical and theoretical chemistry,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1300/1303
Faculty \ School:	Faculty of Science > School of Chemistry, Pharmacy and Pharmacology
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	10 Sep 2024 12:30
Last Modified:	25 Sep 2024 18:08
URI:	https://ueaeprints.uea.ac.uk/id/eprint/96640
DOI:	10.1039/b504293c

Actions (login required)

View Item