Direct synthesis of chiral aziridines from N-tert-butyl-sulfinylketimines

Morton, Daniel, Pearson, David, Field, Robert A. ORCID: https://orcid.org/0000-0001-8574-0275 and Stockman, Robert A. (2006) Direct synthesis of chiral aziridines from N-tert-butyl-sulfinylketimines. Chemical Communications (17). pp. 1833-1835. ISSN 1359-7345

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Abstract

The direct preparation of a range of variously substituted chiral tert-butylsulfinylketimines was achieved in good yield (41-90%), with relatively rapid reaction times (4-15 hours); their synthetic application was examined through the reaction with the ylides derived from trimethylsulfonium iodide and S-allyl tetrahydrothiophenium bromide, affording convenient access to a diverse range of highly substituted chiral aziridines in up to 78% yield and > 90% d.e.

Item Type:	Article
Uncontrolled Keywords:	electronic, optical and magnetic materials,catalysis,ceramics and composites,chemistry(all),surfaces, coatings and films,metals and alloys,materials chemistry ,/dk/atira/pure/subjectarea/asjc/2500/2504
Faculty \ School:	Faculty of Science > School of Chemistry, Pharmacy and Pharmacology
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	10 Sep 2024 12:30
Last Modified:	25 Sep 2024 18:08
URI:	https://ueaeprints.uea.ac.uk/id/eprint/96634
DOI:	10.1039/b601527a

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