Convergent synthesis of a trisaccharide as its 2-(trimethylsilyl)ethyl glycoside related to the flavonoid triglycoside from Gymnema sylvestre

Mukhopadhyay, Balaram and Field, Robert A. ORCID: https://orcid.org/0000-0001-8574-0275 (2006) Convergent synthesis of a trisaccharide as its 2-(trimethylsilyl)ethyl glycoside related to the flavonoid triglycoside from Gymnema sylvestre. Carbohydrate Research, 341 (10). pp. 1697-1701. ISSN 0008-6215

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Abstract

The glycone part of the flavonoid triglycoside, kaempferol 3-O-β-d-glucopyranosyl-(1→4)-α-l-rhamnopyranosyl-(1→6)-β-d-galactopyranoside, has been synthesized in good yield and stereoselectivity using N-iodosuccinimide and HClO4-silica promoted glycosylations of thioglycoside donors.

Item Type: Article
Uncontrolled Keywords: antidiabetic,flavonoids,hclo-silica,analytical chemistry,biochemistry,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1602
Faculty \ School: Faculty of Science > School of Chemistry, Pharmacy and Pharmacology
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Depositing User: LivePure Connector
Date Deposited: 10 Sep 2024 12:30
Last Modified: 25 Sep 2024 18:08
URI: https://ueaeprints.uea.ac.uk/id/eprint/96632
DOI: 10.1016/j.carres.2006.03.019

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