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Madlool, Atheer M., Wingrove, Grace E., Paran Rutterford, Ben J., Malik, Ahmad, Butcher, Heather K. and Wright, Joseph A. 
ORCID: https://orcid.org/0000-0001-9603-1001
(2023)
Improved access to ‘butterfly’ di-iron dithiolates Fe2(µ-SR)2(CO)6 and their mono- and bis(phosphine) adducts.
ChemistrySelect, 8 (33).
ISSN 2365-6549
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Abstract
A series of Fe2(μ-SR)2(CO)6 complexes with a range of substituents have been prepared and characterised. This facile route provides improved access to pure ‘open’ Fe2(μ-SR)2(CO)6 systems with mono- and bis-substitution of PR3 ligands without using decarbonylation reagent. Comparisons of synthesis routes, solid-state structures, oxidative electrochemistry further insights into the chemistry of these systems have been reported.
| Item Type: | Article |
|---|---|
| Additional Information: | Research Funding: Leverhulme Trust. Grant Number: RPG-2019-115; EPSRC. Grant Number: EP/S005854/1 |
| Uncontrolled Keywords: | [fefe]-hydrogenases,hydrogen production,iron–sulfur clusters,organometallics,chemistry(all) ,/dk/atira/pure/subjectarea/asjc/1600 |
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 14 Aug 2023 16:30 |
| Last Modified: | 27 Nov 2024 10:40 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/92860 |
| DOI: | 10.1002/slct.202302935 |
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