A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis

Fateeva, Alexandra, Chater, Philip A., Ireland, Christopher P., Tahir, Asif A., Khimyak, Yaroslav Z., Wiper, Paul V., Darwent, James R. and Rosseinsky, Matthew J. (2012) A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis. Angewandte Chemie - International Edition, 51 (30). pp. 7440-7444. ISSN 1433-7851

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Abstract

Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.

Item Type: Article
Uncontrolled Keywords: heterogeneous catalysis,hydrogen production,metal-organic frameworks,porphyrinoids,catalysis,chemistry(all) ,/dk/atira/pure/subjectarea/asjc/1500/1503
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Depositing User: LivePure Connector
Date Deposited: 09 Jul 2021 07:29
Last Modified: 28 Jul 2021 00:42
URI: https://ueaeprints.uea.ac.uk/id/eprint/80481
DOI: 10.1002/anie.201202471

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