A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis

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Fateeva, Alexandra, Chater, Philip A., Ireland, Christopher P., Tahir, Asif A., Khimyak, Yaroslav Z. ORCID: https://orcid.org/0000-0003-0424-4128, Wiper, Paul V., Darwent, James R. and Rosseinsky, Matthew J. (2012) A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis. Angewandte Chemie - International Edition, 51 (30). pp. 7440-7444. ISSN 1433-7851

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Abstract

Light-harvesting MOFs: A new porous porphyrinic metal-organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible-light photocatalytic activity of this porphyrin-based material is shown for the sacrificial hydrogen evolution from water.

Item Type:	Article
Uncontrolled Keywords:	heterogeneous catalysis,hydrogen production,metal-organic frameworks,porphyrinoids,catalysis,chemistry(all),sdg 7 - affordable and clean energy ,/dk/atira/pure/subjectarea/asjc/1500/1503
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	09 Jul 2021 07:29
Last Modified:	23 Oct 2022 02:37
URI:	https://ueaeprints.uea.ac.uk/id/eprint/80481
DOI:	10.1002/anie.201202471

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