Synthesis and characterization of two novel mesolamellar aluminophosphates

Khimyak, Yaroslav Z. ORCID: https://orcid.org/0000-0003-0424-4128 and Klinowski, Jacek (1998) Synthesis and characterization of two novel mesolamellar aluminophosphates. Chemistry of Materials, 10 (8). pp. 2258-2265. ISSN 0897-4756

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Abstract

Two new mesolamellar aluminophosphates, designated L1 and L2, have been synthesized by supramolecular templating from aqueous solutions containing a cationic surfactant and tetraalkylammonium hydroxide. The structure, morphology, and properties of the products have been examined by XRD, SEM, solid-state NMR, thermogravimetry and FTIR and optimal synthesis conditions have been established. Although the compositions of the starting mixtures for the synthesis of L1 and L2 are similar, the structures of the two materials are different. In L2 phosphorus is coordinated to four AlO4 tetrahedra; this is the most significant difference between the two products, responsible for the higher thermal stability of L2. The synthesis of L2 requires higher temperatures than that of L1.

Item Type:	Article
Uncontrolled Keywords:	chemistry(all),chemical engineering(all),materials chemistry ,/dk/atira/pure/subjectarea/asjc/1600
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	09 Jul 2021 07:28
Last Modified:	23 Oct 2022 02:37
URI:	https://ueaeprints.uea.ac.uk/id/eprint/80477
DOI:	10.1021/cm9807081

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