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Ganin, Alexey Yu., Takabayashi, Yasuhiro, Bridges, Craig A., Khimyak, Yaroslav Z. 
ORCID: https://orcid.org/0000-0003-0424-4128, Margadonna, Serena, Prassides, Kosmas and Rosseinsky, Matthew J.
(2006)
Methylaminated potassium fulleride, (CH3NH2)K 3C60: Towards hyperexpanded fulleride lattices.
Journal of the American Chemical Society, 128 (46).
pp. 14784-14785.
ISSN 0002-7863
Abstract
Co-intercalation of methylamine molecules into the cubic K3C60 lattice affords the fulleride (CH3NH2)K3C60, which was characterized by Raman and MAS 13C and 1H NMR spectroscopy. The high-resolution synchrotron X-ray powder diffraction technique was employed to determine its crystal structure at ambient temperature. We find that CH3NH2 bonds to K+ ions residing in the pseudo-octahedral interstices, thereby providing an efficient and facile route to hyperexpanded close-packed strongly anisotropic fulleride lattices, while retaining the electronic contact between the C603- anions. Preliminary evidence for the occurrence of a transition to an antiferromagnetic state at low temperature is also presented, consistent with the proximity of the present system to the metal-insulator boundary of the electronic phase diagram of C603- fullerides.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | catalysis,chemistry(all),biochemistry,colloid and surface chemistry ,/dk/atira/pure/subjectarea/asjc/1500/1503 |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 09 Jul 2021 07:28 |
| Last Modified: | 23 Oct 2022 02:37 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/80457 |
| DOI: | 10.1021/ja066295j |
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