The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

Boomishankar, Ramamoorthy, Ledger, Joanne, Guilbaud, Jean-Baptiste, Campbell, Neil L., Bacsa, John, Bonar-Law, Richard, Khimyak, Yaroslav Z. ORCID: and Steiner, Alexander (2007) The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+. Chemical Communications (48). pp. 5152-5154. ISSN 1359-7345

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The cyclotriphosphazene P3N3Cl6 reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P3N3(DMAP) 6]Cl6·19CHCl3 comprising [P 3N3(DMAP)6]6+ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

Item Type: Article
Uncontrolled Keywords: catalysis,electronic, optical and magnetic materials,ceramics and composites,chemistry(all),surfaces, coatings and films,metals and alloys,materials chemistry ,/dk/atira/pure/subjectarea/asjc/1500/1503
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Depositing User: LivePure Connector
Date Deposited: 09 Jul 2021 07:28
Last Modified: 23 Oct 2022 02:37
DOI: 10.1039/b713847d

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