The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+

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Boomishankar, Ramamoorthy, Ledger, Joanne, Guilbaud, Jean-Baptiste, Campbell, Neil L., Bacsa, John, Bonar-Law, Richard, Khimyak, Yaroslav Z. ORCID: https://orcid.org/0000-0003-0424-4128 and Steiner, Alexander (2007) The N-donor stabilised cyclotriphosphazene hexacation [P3N3(DMAP)6]6+. Chemical Communications (48). pp. 5152-5154. ISSN 1359-7345

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Abstract

The cyclotriphosphazene P3N3Cl6 reacts with six equivalents of DMAP (4-(dimethylamino)pyridine) in superheated chloroform to form crystals of composition [P3N3(DMAP) 6]Cl6·19CHCl3 comprising [P 3N3(DMAP)6]6+ ions, which host five chloride ions in basket-type cavities on either side of the ring and at equatorial positions via tetradentate ortho-H-donor arrangements.

Item Type:	Article
Uncontrolled Keywords:	catalysis,electronic, optical and magnetic materials,ceramics and composites,chemistry(all),surfaces, coatings and films,metals and alloys,materials chemistry ,/dk/atira/pure/subjectarea/asjc/1500/1503
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	09 Jul 2021 07:28
Last Modified:	23 Oct 2022 02:37
URI:	https://ueaeprints.uea.ac.uk/id/eprint/80452
DOI:	10.1039/b713847d

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