Magnetic circular dichroism of symmetry and spin forbidden transitions of high-spin metal ions

Oganesyan, Vasily S. and Thomson, Andrew J. (2000) Magnetic circular dichroism of symmetry and spin forbidden transitions of high-spin metal ions. Journal of Chemical Physics, 113 (12). pp. 5003-5017. ISSN 0021-9606

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Abstract

A previously developed method to analyze magnetic circular dichroism (MCD) is extended to analyze the near infrared region of ligand-field (LF) spin-forbidden transitions of the type 6A1→4E, 4A2, 4B2 of pseudo-tetrahedral high-spin Fe(III), S=5/2, in the protein oxidized rubredoxin. It is demonstrated that for some specific state of a paramagnetic center and under appropriate experimental conditions, the MCD of spin or symmetry forbidden transitions becomes comparable in magnitude to those of allowed transitions.

Item Type: Article
Uncontrolled Keywords: physics and astronomy(all),physical and theoretical chemistry ,/dk/atira/pure/subjectarea/asjc/3100
Faculty \ School: Faculty of Science > School of Chemistry
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Depositing User: LivePure Connector
Date Deposited: 08 Jul 2021 00:06
Last Modified: 30 Sep 2021 16:37
URI: https://ueaeprints.uea.ac.uk/id/eprint/80437
DOI: 10.1063/1.1289531

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