Magnetic circular dichroism of symmetry and spin forbidden transitions of high-spin metal ions

Oganesyan, Vasily S. ORCID: https://orcid.org/0000-0002-8738-1146 and Thomson, Andrew J. (2000) Magnetic circular dichroism of symmetry and spin forbidden transitions of high-spin metal ions. Journal of Chemical Physics, 113 (12). pp. 5003-5017. ISSN 0021-9606

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Abstract

A previously developed method to analyze magnetic circular dichroism (MCD) is extended to analyze the near infrared region of ligand-field (LF) spin-forbidden transitions of the type 6A1→4E, 4A2, 4B2 of pseudo-tetrahedral high-spin Fe(III), S=5/2, in the protein oxidized rubredoxin. It is demonstrated that for some specific state of a paramagnetic center and under appropriate experimental conditions, the MCD of spin or symmetry forbidden transitions becomes comparable in magnitude to those of allowed transitions.

Item Type:	Article
Uncontrolled Keywords:	physics and astronomy(all),physical and theoretical chemistry ,/dk/atira/pure/subjectarea/asjc/3100
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Centre for Photonics and Quantum Science
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	08 Jul 2021 00:06
Last Modified:	09 Feb 2023 13:49
URI:	https://ueaeprints.uea.ac.uk/id/eprint/80437
DOI:	10.1063/1.1289531

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