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Oganesyan, Vasily S. 
ORCID: https://orcid.org/0000-0002-8738-1146 and Thomson, Andrew J.
(2000)
Magnetic circular dichroism of symmetry and spin forbidden transitions of high-spin metal ions.
Journal of Chemical Physics, 113 (12).
pp. 5003-5017.
ISSN 0021-9606
Abstract
A previously developed method to analyze magnetic circular dichroism (MCD) is extended to analyze the near infrared region of ligand-field (LF) spin-forbidden transitions of the type 6A1→4E, 4A2, 4B2 of pseudo-tetrahedral high-spin Fe(III), S=5/2, in the protein oxidized rubredoxin. It is demonstrated that for some specific state of a paramagnetic center and under appropriate experimental conditions, the MCD of spin or symmetry forbidden transitions becomes comparable in magnitude to those of allowed transitions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | physics and astronomy(all),physical and theoretical chemistry ,/dk/atira/pure/subjectarea/asjc/3100 |
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Centre for Photonics and Quantum Science |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 08 Jul 2021 00:06 |
| Last Modified: | 25 Sep 2024 15:40 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/80437 |
| DOI: | 10.1063/1.1289531 |
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