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Deschamps, Damien, Lohier, Jean-François, Richards, Christopher J. 
ORCID: https://orcid.org/0000-0001-7899-4082, Gaumont, Annie-Claude and Perrio, Stéphane
(2021)
Functionalization of [2.2]paracyclophanes via a reductive sulfanylation reaction.
The Journal of Organic Chemistry, 86 (1).
pp. 507-514.
ISSN 0022-3263
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Abstract
An expeditious route to planar chiral sulfur-based scaffolds has been achieved in two operational steps from cheap and commercial [2.2]paracyclophane hydrocarbon. The sulfur atom was introduced in a specific benzylic position of the [2.2]paracyclophane according to a reductive sulfanylation reaction, which proceeds under two complementary reaction conditions with either the BF3·OEt2/Et3SiH or TFA/BH3·THF combinations. The study was completed by the development of a highly efficient resolution approach by HPLC.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 2* ,/dk/atira/pure/researchoutput/REFrank/2_ |
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 09 Mar 2021 00:41 |
| Last Modified: | 01 Oct 2024 23:55 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/79402 |
| DOI: | 10.1021/acs.joc.0c02235 |
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