Ruthenium carbamoyl complexes: coordination chemistry and CO release

Wright, Mark A., O'Connell, Maria A. ORCID: https://orcid.org/0000-0002-0267-0951 and Wright, Joseph A. ORCID: https://orcid.org/0000-0001-9603-1001 (2021) Ruthenium carbamoyl complexes: coordination chemistry and CO release. Inorganica Chimica Acta, 520. ISSN 0020-1693

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Abstract

Reaction of Ru(CO) 4Br 2 with a series of heterocyclic amines leads to a family of ruthenium carbamoyl complexes. These are analogous to the related ferracyclic systems reported by us as potential photoCORM systems (Chem. Commun., 2020, 56, 4300–4303). In contrast to the iron compounds, the ruthenium carbamoyls release CO only when irradiated in the UV, and show no activity as anti-inflammatory agents.

Item Type: Article
Uncontrolled Keywords: anti-inflammatory agents,metal carbonyls,photocorms,physical and theoretical chemistry,inorganic chemistry,materials chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1606
Faculty \ School: Faculty of Science > School of Pharmacy
Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Molecular and Tissue Pharmacology
Faculty of Science > Research Groups > Chemistry of Light and Energy
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Faculty of Science > Research Groups > Energy Materials Laboratory
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Depositing User: LivePure Connector
Date Deposited: 02 Feb 2021 01:02
Last Modified: 22 Oct 2022 08:33
URI: https://ueaeprints.uea.ac.uk/id/eprint/79122
DOI: 10.1016/j.ica.2021.120283

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