Planar chiral palladacycle precatalysts for asymmetric synthesis

Arthurs, Ross A., Hughes, David L. and Richards, Christopher J. (2020) Planar chiral palladacycle precatalysts for asymmetric synthesis. Organic & Biomolecular Chemistry, 18 (28). pp. 5466-5472. ISSN 1477-0520

[img]
Preview
PDF (Published_Version) - Published Version
Available under License Creative Commons Attribution Non-commercial.

Download (1MB) | Preview

Abstract

Chiral non-racemic palladacycles were employed as precatalysts for Pd(0) mediated asymmetric synthesis. Addition of HPAr2/base to a ferrocenyloxazoline planar chiral palladacycle resulted in ligand synthesis and palladium capture to give a bidentate Phosferrox/Pd(0) complex. A series of these complexes were generated in situ and applied successfully as catalysts for asymmetric allylic alkylation.

Item Type: Article
Uncontrolled Keywords: biochemistry,physical and theoretical chemistry,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1300/1303
Faculty \ School: Faculty of Science > School of Chemistry
Related URLs:
Depositing User: LivePure Connector
Date Deposited: 12 Aug 2020 23:54
Last Modified: 18 Sep 2020 23:52
URI: https://ueaeprints.uea.ac.uk/id/eprint/76416
DOI: 10.1039/d0ob01331e

Actions (login required)

View Item View Item