Planar chiral palladacycle precatalysts for asymmetric synthesis

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Arthurs, Ross A., Hughes, David L. and Richards, Christopher J. ORCID: https://orcid.org/0000-0001-7899-4082 (2020) Planar chiral palladacycle precatalysts for asymmetric synthesis. Organic & Biomolecular Chemistry, 18 (28). pp. 5466-5472. ISSN 1477-0520

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Abstract

Chiral non-racemic palladacycles were employed as precatalysts for Pd(0) mediated asymmetric synthesis. Addition of HPAr2/base to a ferrocenyloxazoline planar chiral palladacycle resulted in ligand synthesis and palladium capture to give a bidentate Phosferrox/Pd(0) complex. A series of these complexes were generated in situ and applied successfully as catalysts for asymmetric allylic alkylation.

Item Type:	Article
Uncontrolled Keywords:	biochemistry,physical and theoretical chemistry,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1300/1303
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	12 Aug 2020 23:54
Last Modified:	22 Oct 2022 06:35
URI:	https://ueaeprints.uea.ac.uk/id/eprint/76416
DOI:	10.1039/d0ob01331e

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