A novel tri-unsaturated highly branched isoprenoid (HBI) alkene from the marine diatom Navicula salinicola

Gao, Simin, Smik, Lukas, Kulikovskiy, Maxim, Shkurina, Nataliya, Gusev, Evgeniy, Pedentchouk, Nikolai ORCID: https://orcid.org/0000-0002-2923-966X, Mock, Thomas ORCID: https://orcid.org/0000-0001-9604-0362 and Belt, Simon T. (2020) A novel tri-unsaturated highly branched isoprenoid (HBI) alkene from the marine diatom Navicula salinicola. Organic Geochemistry, 146. ISSN 0146-6380

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Abstract

A novel tri-unsaturated C25 highly branched isoprenoid (HBI) alkene has been identified in a laboratory culture of the diatom Navicula salinicola and its structure determined using a combination of NMR spectroscopy and gas chromatography–mass spectrometry (GC–MS). This represents the first report of a C25 HBI in a marine diatom from the Navicula genus, although a different tri-unsaturated C25 HBI has been reported previously in the freshwater species N. sclesvicensis and unspecified HBIs have been identified in the brackish N. phyllepta. The newly characterised HBI contains a relatively unusual conjugated diene sub-unit, a structural feature only previously reported in some HBIs biosynthesised by a further marine diatom, Haslea ostrearia.

Item Type: Article
Uncontrolled Keywords: sdg 14 - life below water ,/dk/atira/pure/sustainabledevelopmentgoals/life_below_water
Faculty \ School: Faculty of Science > School of Environmental Sciences
Faculty of Science > School of Biological Sciences
UEA Research Groups: Faculty of Science > Research Groups > Environmental Biology
Faculty of Science > Research Groups > Geosciences
Faculty of Science > Research Centres > Centre for Ecology, Evolution and Conservation
Faculty of Science > Research Groups > Centre for Ocean and Atmospheric Sciences
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Depositing User: LivePure Connector
Date Deposited: 28 May 2020 00:20
Last Modified: 30 Jul 2023 23:45
URI: https://ueaeprints.uea.ac.uk/id/eprint/75321
DOI: 10.1016/j.orggeochem.2020.104050

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