Allene-derived gold and platinum complexes: synthesis and first applications in catalysis

Maliszewska, Hanna, Hughes, David and Munoz-Herranz, Maria Paz (2020) Allene-derived gold and platinum complexes: synthesis and first applications in catalysis. Dalton Transactions, 49 (13). pp. 4034-4038. ISSN 1477-9226

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Abstract

We report here the synthesis, full characterisation and first application in catalysis of novel Au(I), Au(III) and Pt(II) carbene-type complexes formed from bis(pyridyl)allenes. The catalytic activity of the new Au(I)-complexes in the cylisation of 1,6-enynes, benchmark reaction for new Au and Pt complexes, was comparable to Au(I)-state-of-the-art catalysts used in these reactions. Reactions with the new Au(III)- and Pt(II)-complexes ocurred under milder conditions than the reported with AuCl3 and PtCl2.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
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Depositing User: LivePure Connector
Date Deposited: 29 Feb 2020 08:36
Last Modified: 22 May 2020 00:19
URI: https://ueaeprints.uea.ac.uk/id/eprint/74354
DOI: 10.1039/D0DT00665C

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