Maliszewska, Hanna, Hughes, David and Munoz-Herranz, Maria Paz ORCID: https://orcid.org/0000-0001-9037-349X (2020) Allene-derived gold and platinum complexes: synthesis and first applications in catalysis. Dalton Transactions, 49 (13). pp. 4034-4038. ISSN 1477-9226
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Abstract
We report here the synthesis, full characterisation and first application in catalysis of novel Au(I), Au(III) and Pt(II) carbene-type complexes formed from bis(pyridyl)allenes. The catalytic activity of the new Au(I)-complexes in the cylisation of 1,6-enynes, benchmark reaction for new Au and Pt complexes, was comparable to Au(I)-state-of-the-art catalysts used in these reactions. Reactions with the new Au(III)- and Pt(II)-complexes ocurred under milder conditions than the reported with AuCl3 and PtCl2.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Chemistry |
UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis |
Related URLs: | |
Depositing User: | LivePure Connector |
Date Deposited: | 29 Feb 2020 08:36 |
Last Modified: | 22 Oct 2022 05:54 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/74354 |
DOI: | 10.1039/D0DT00665C |
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