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Gardiner, William, Camilleri, Matthew, Martinez Lozano, Luis Angel, Bew, Sean 
ORCID: https://orcid.org/0000-0002-9087-9463 and Stephenson, G. Richard ORCID: https://orcid.org/0000-0003-1487-9178
(2018)
Upper-rim monofunctionalisation in the synthesis of triazole- and disulfide-linked multicalix[4]- and -[6]arenes.
Chemistry - A European Journal, 24 (71).
pp. 19089-19097.
ISSN 0947-6539
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Abstract
Covalently linked multiple calixarenes are valued in supramolecular chemistry. We report an easy and versatile synthetic route to covalently linked double and triple calix[4]arene and calix[6]arenes by a novel DMF‐controlled selective alkylation of a convenient and readily available upper‐rim dimethylaminomethyl‐substituted tetrahydroxy calix[4]arene and ‐[6]arenes. Synthetic routes to upper‐rim functionalised redox active disulfide‐linked double‐, tetra‐ and peptidohybrid‐calixarenes employing either redox chemistry (CH2SH) or thiolates (CH2S–) are also opened up from the same key starting material.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 01 Nov 2018 13:31 |
| Last Modified: | 19 Dec 2024 00:55 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/68734 |
| DOI: | 10.1002/chem.201804755 |
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