Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes
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ToolsFernandez-Cestau, Julio, Rocchigiani, Luca, Pintus, Anna, Rama, Raquel J., Budzelaar, Peter H. M. and Bochmann, Manfred (2018) Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes. Chemical Communications, 54 (81). pp. 11447-11450. ISSN 1359-7345
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Abstract
Isocyanides insert into gold(III)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| Depositing User: | LivePure Connector |
| Date Deposited: | 26 Sep 2018 14:30 |
| Last Modified: | 09 May 2020 23:52 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/68362 |
| DOI: | 10.1039/C8CC06409A |
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