Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes

Fernandez-Cestau, Julio, Rocchigiani, Luca, Pintus, Anna, Rama, Raquel J., Budzelaar, Peter H. M. and Bochmann, Manfred (2018) Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes. Chemical Communications, 54 (81). pp. 11447-11450. ISSN 1359-7345

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Abstract

Isocyanides insert into gold(III)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: LivePure Connector
Date Deposited: 26 Sep 2018 14:30
Last Modified: 09 May 2020 23:52
URI: https://ueaeprints.uea.ac.uk/id/eprint/68362
DOI: 10.1039/C8CC06409A

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