Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes

Fernandez-Cestau, Julio, Rocchigiani, Luca, Pintus, Anna, Rama, Raquel J., Budzelaar, Peter H. M. and Bochmann, Manfred (2018) Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes. Chemical Communications, 54 (81). pp. 11447-11450. ISSN 1359-7345

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Abstract

Isocyanides insert into gold(III)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	LivePure Connector
Date Deposited:	26 Sep 2018 14:30
Last Modified:	06 Feb 2025 08:00
URI:	https://ueaeprints.uea.ac.uk/id/eprint/68362
DOI:	10.1039/C8CC06409A

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