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Barad, Seema, Kreouzis, Theo, Cammidge, Andrew N. 
ORCID: https://orcid.org/0000-0001-7912-4310, Cook, Michael J. and Ray, Asim K.
(2018)
Newly synthesised gadolinium bis-phthalocyanine sandwich complex: Ambipolar organic semiconductor.
Semiconductor Science and Technology, 33.
ISSN 0268-1242
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Abstract
Time of flight (TOF) photocurrent transient studies on 5µm thick solution processed films of novel non-peripherally octa-octyl-substituted liquid crystalline gadolinium bis-1,4,8,11,15,18,22,25-octakis(octyl) phthalocyanines (8GdPc2) provide a quantitative analysis of the intrinsic ambipolar charge transport relative to mesomorphic structure of this lanthanide compound. Characteristic liquid crystalline phases of these molecules have been identified from differential scanning calorimetry supported by observation from the UV-visible absorption, showing crystal-columnar mesophase and columnar mesophase-isotropic liquid transitions at 64.2°C and 162°C, respectively. The TOF carrier mobility is found to be structure dependent and highest values of 4.73×10−6m2/Vs and 1.6×10−6m2/Vs have been estimated for hole and electron mobilities for hexagonally packed, columnar structures of the spin-coated films. These results are exploitable for development of single molecule based all organic complimentary analogue and digital circuits with tunable field effect performance.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 31 Jul 2018 15:30 |
| Last Modified: | 25 Sep 2024 13:34 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/67903 |
| DOI: | 10.1088/1361-6641/aad42d |
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