Arene C-H activation by gold(III): Solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate
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ToolsRocchigiani, Luca, Fernandez Cestau, Julio, Budzelaar, Peter and Bochmann, Manfred (2017) Arene C-H activation by gold(III): Solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate. Chemical Communications, 53 (31). pp. 4358-4361. ISSN 1359-7345
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Abstract
Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(III) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(III)-arene interactions commensurate with intermediates postulated previously for CMD-type arene activation.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| Depositing User: | Pure Connector |
| Date Deposited: | 21 Apr 2017 05:10 |
| Last Modified: | 10 Nov 2021 05:44 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/63269 |
| DOI: | 10.1039/C7CC01628J |
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