Cross-dehydrogenative-coupling of alkoxybenzenes with toluenes: Copper(II) halide mediated tandem halo/benzylation of arenes

Storr, Thomas E., Teskey, Christopher J. and Greaney, Michael F. (2016) Cross-dehydrogenative-coupling of alkoxybenzenes with toluenes: Copper(II) halide mediated tandem halo/benzylation of arenes. Chemistry - A European Journal, 22 (50). pp. 18169-18178. ISSN 0947-6539

Full text not available from this repository. (Request a copy)

Abstract

A cross-dehydrogenative-coupling of alkoxybenzenes and toluenes with concomitant halogenation is reported. Conditions employed were the use of stoichiometric copper halide salts and dialkylperoxides to afford a range of bromoalkoxydi- and triarylmethanes. Preliminary mechanistic studies suggest that the in situ production of haloarenes (or dihaloarenes) followed by a copper-mediated coupling of a benzylic radical is operational.

Item Type:	Article
Uncontrolled Keywords:	c−h activation,cross-dehydrogenative-coupling,diarylmethane,homogeneous catalysis,tandem reactions
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Related URLs:	https://www.research.manchester.ac.uk/po... http://doi.wiley.com/10.1002/chem.201603...
Depositing User:	Pure Connector
Date Deposited:	14 Mar 2017 01:41
Last Modified:	05 May 2024 01:14
URI:	https://ueaeprints.uea.ac.uk/id/eprint/62946
DOI:	10.1002/chem.201603783

Actions (login required)

View Item