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Glowacka, Paulina C., Maindron, Nicolas, Stephenson, G. Richard 
ORCID: https://orcid.org/0000-0003-1487-9178, Romieu, Anthony, Renard, Pierre-Yves and Emery, Flavio da Silva
(2016)
Synthesis and photophysical properties of iron-carbonyl complex-coumarin conjugates as potential bimodal IR-fluorescent probes.
Tetrahedron Letters, 57 (45).
4991–4996.
ISSN 0040-4039
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Abstract
An expedient synthesis of the first examples of iron-carbonyl complex-coumarin conjugates is reported. 7-Amino/7-hydroxycoumarin derivatives have been readily derivatized through an easily implemented single-step reaction involving the tricarbonyl(η5-cyclohexadienyl)iron(1+) cation [(C6H7)Fe(CO)3]+. The scope and limitations of this N-/O-alkylation reaction were also investigated. The fluorescence properties of these novel metal-carbonyl complexes have been studied and support their further use as valuable building blocks in the design of bimodal contrast agents for combined vibrational and fluorescence imaging.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | coumarins,dual imaging probes,fluorescence,infrared,iron-carbonyl complexes |
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis |
| Related URLs: | |
| Depositing User: | Pure Connector |
| Date Deposited: | 05 Oct 2016 16:00 |
| Last Modified: | 22 Oct 2022 01:40 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/60759 |
| DOI: | 10.1016/j.tetlet.2016.09.091 |
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