Crystal structure of sodium (1S )-D-lyxit-1-ylsulfonate

Haines, Alan and Hughes, David (2016) Crystal structure of sodium (1S )-D-lyxit-1-ylsulfonate. Acta Crystallographica Section E: Crystallographic Communications, 72 (5). pp. 628-631. ISSN 2056-9890

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Abstract

The title compound, Na+·C5H11O8S- [systematic name: sodium (1S,2S,3S,4R)-1,2,3,4,5-penta­hydroxy­pentane-1-sulfonate], is formed by reaction of D-lyxose with sodium bis­ulfite (sodium hydrogen sulfite) in water. The anion has an open-chain structure in which one of the oxygen atoms of the sulfonate residue, the S atom, the C atoms of the sugar chain and the O atom of the hy­droxy­methyl group form an essentially planar zigzag chain with the corresponding torsion angles lying between 179.80 (11) and 167.74 (14)°. A three-dimensional bonding network exists in the crystal structure involving hexa­coordination of sodium ions by O atoms, three of which are provided by a single D-lyxose-sulfonate unit and the other three by two sulfonate groups and one hy­droxy­methyl group, each from separate units of the adduct. Extensive inter­molecular O-H...O hydrogen bonding supplements this bonding network.

Item Type:	Article
Additional Information:	This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Uncontrolled Keywords:	crystal structure,d-lyxose bisulfite adduct,sodium hydrogen sulfite,sodium metabisulfite
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
Depositing User:	Pure Connector
Date Deposited:	12 May 2016 10:00
Last Modified:	21 Dec 2024 00:50
URI:	https://ueaeprints.uea.ac.uk/id/eprint/58667
DOI:	10.1107/S2056989016005375

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