Detection of transient intermediates generated from subsite analogues of [FeFe]-hydrogenases

Hunt, Neil T., Wright, Joseph A. ORCID: https://orcid.org/0000-0001-9603-1001 and Pickett, Christopher (2016) Detection of transient intermediates generated from subsite analogues of [FeFe]-hydrogenases. Inorganic Chemistry, 55 (2). pp. 399-410. ISSN 0020-1669

[thumbnail of FeFe-review-final] Microsoft Word (FeFe-review-final) - Accepted Version
Download (2MB)

Abstract

This article reviews the application of transient techniques in the elucidation of electron, proton and photon chemistry related to the catalytic subsite of [FeFe]-hydrogenase from the perspective of research in this area carried out at the UEA and Strathclyde laboratories. The detection of mixed valence states, bridging CO intermediates, paramagnetic hydrides and coordinatively unsaturated species has both informed an understanding of the biological catalysis and stimulated the search for stable analogues of key structural motifs likely involved in turnover states.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017)
Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Faculty of Science > Research Groups > Chemistry of Light and Energy
Faculty of Science > Research Groups > Energy Materials Laboratory
Depositing User: Pure Connector
Date Deposited: 21 Jan 2016 13:00
Last Modified: 22 Oct 2022 00:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/56723
DOI: 10.1021/acs.inorgchem.5b02477

Actions (login required)

View Item View Item