Intra- and inter-molecular C-H⋯F-C and N-H⋯F-C hydrogen bonding in secondary amine adducts of B(C6F5)3: relevance to key interactions in alkene polymerisation catalysis

Mountford, Andrew J., Hughes, David L. and Lancaster, Simon J. (2003) Intra- and inter-molecular C-H⋯F-C and N-H⋯F-C hydrogen bonding in secondary amine adducts of B(C6F5)3: relevance to key interactions in alkene polymerisation catalysis. Chemical Communications (17). pp. 2148-2149. ISSN 1359-7345

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Abstract

The reactions between the cyclic sec. amines pyrrolidine and piperidine with B(C6F5)3 yield Lewis acid-base adducts with both intra- and inter-molecular hydrogen bonding interactions between C–H and N–H groups and aryl-fluorines in the solid state.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Pure Connector
Date Deposited:	11 Jan 2016 12:00
Last Modified:	15 Oct 2025 22:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/56169
DOI:	10.1039/b305613a

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