Synthesis and Luminescence Modulation of Pyrazine-Based Gold(III) Pincer Complexes

Fernandez Cestau, Julio, Bertrand, Benoît, Blaya, Maria, Jones, Garth A., Penfold, Thomas J. and Bochmann, Manfred (2015) Synthesis and Luminescence Modulation of Pyrazine-Based Gold(III) Pincer Complexes. Chemical Communications, 51 (93). pp. 16629-16632. ISSN 1359-7345

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Abstract

The first examples of pyrazine-based gold(III) pincer complexes have been synthesized; their intense photoemissions can be modified by interactions with the non-coordinating pyrazine-N atom. Luminescence modulation is possible without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF)

Item Type: Article
Additional Information: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Pure Connector
Date Deposited: 05 Oct 2015 14:50
Last Modified: 22 Apr 2020 00:32
URI: https://ueaeprints.uea.ac.uk/id/eprint/54572
DOI: 10.1039/c5cc07523h

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