Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes

Fernandez Cestau, Julio, Bertrand, Benoît, Blaya, Maria, Jones, Garth A., Penfold, Thomas J. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2015) Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes. Chemical Communications, 51 (93). pp. 16629-16632. ISSN 1359-7345

Preview

PDF (C5CC07523H ASAP) - Published Version Available under License Creative Commons Attribution. Download (1MB) | Preview

Abstract

The first examples of pyrazine-based gold(III) pincer complexes have been synthesized; their intense photoemissions can be modified by interactions with the non-coordinating pyrazine-N atom. Luminescence modulation is possible without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF)

Item Type:	Article
Additional Information:	This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Centre for Photonics and Quantum Science
Depositing User:	Pure Connector
Date Deposited:	05 Oct 2015 14:50
Last Modified:	24 Sep 2024 11:24
URI:	https://ueaeprints.uea.ac.uk/id/eprint/54572
DOI:	10.1039/c5cc07523h

Downloads

Actions (login required)

View Item