Network formation mechanisms in conjugated microporous polymers

Laybourn, Andrea, Dawson, Robert, Clowes, Rob, Hasell, Tom, Cooper, Andrew I., Khimyak, Yaroslav Z. ORCID: https://orcid.org/0000-0003-0424-4128 and Adams, Dave J. (2014) Network formation mechanisms in conjugated microporous polymers. Polymer Chemistry, 5 (21). pp. 6325-6333. ISSN 1759-9954

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Abstract

We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira–Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.

Item Type: Article
Faculty \ School: Faculty of Science > School of Pharmacy (former - to 2024)
UEA Research Groups: Faculty of Science > Research Groups > Drug Delivery and Pharmaceutical Materials (former - to 2017)
Faculty of Science > Research Groups > Pharmaceutical Materials and Soft Matter
Depositing User: Pure Connector
Date Deposited: 24 Jul 2015 22:50
Last Modified: 17 Oct 2024 00:12
URI: https://ueaeprints.uea.ac.uk/id/eprint/53723
DOI: 10.1039/C4PY00647J

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