Sodium (1R)-D-glucit-1-ylsulfonate monohydrate

Haines, Alan H. and Hughes, David L. (2012) Sodium (1R)-D-glucit-1-ylsulfonate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 68 (4). m377-m378. ISSN 1600-5368

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Abstract

The title salt, Na+·C6H13O9S-·H2O, crystallizes with three independent cations, molecular anions and solvent water molecules in the asymmetric unit. This crystalline monohydrate addition product, formed by reaction of D-glucose and sodium hydrogen sulfite in water, forms a three-dimensional network through complex cation coordination and extensive intermolecular hydrogen bonding. Each of the independent molecules has an open-chain structure with the carbon chains adopting a sickle-like conformation, similar to that found in the potassium salt [Cole et al. (2001). Carbohydr. Res. 335, 1-10], but there are significant differences in the patterns of complexation.

Item Type:	Article
Additional Information:	Published in an open access journal with a licence identical to a Creative Commons Attribution Licence; see http://journals.iucr.org/services/oa/oalicenceshort.html
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
Depositing User:	Pure Connector
Date Deposited:	27 Aug 2014 13:34
Last Modified:	25 Sep 2024 11:27
URI:	https://ueaeprints.uea.ac.uk/id/eprint/49991
DOI:	10.1107/S1600536812007210

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