The Third Hydrogenase: A Ferracyclic Carbamoyl with Close Structural Analogy to the Active Site of Hmd

Turrell, Peter J., Wright, Joseph A., Peck, Jamie N. T., Oganesyan, Vasily S. and Pickett, Christopher J. (2010) The Third Hydrogenase: A Ferracyclic Carbamoyl with Close Structural Analogy to the Active Site of Hmd. Angewandte Chemie International Edition, 49 (41). pp. 7508-7511. ISSN 1433-7851

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Abstract

The synthesis of a close structural analogue of the active site of [Fe]-hydrogenase is described (see structure; C gray, H dark blue, Fe green, N light blue, O red, S yellow). Nature most probably constructs the five membered ferracyclic ring to poise the 2-hydroxy pyridine substituent in a position to assist the heterolytic cleavage of dihydrogen, and the accessibility of the analogue should now provide opportunities for probing this.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
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Depositing User: Pure Connector
Date Deposited: 18 Dec 2013 12:40
Last Modified: 21 Apr 2020 22:44
URI: https://ueaeprints.uea.ac.uk/id/eprint/47070
DOI: 10.1002/anie.v49:41

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