A thermally stable gold(III) hydride: Synthesis, reactivity, and reductive condensation as a route to gold(II) complexes

Roşca, Dragoş-Adrian, Smith, Dan A., Hughes, David L. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2012) A thermally stable gold(III) hydride: Synthesis, reactivity, and reductive condensation as a route to gold(II) complexes. Angewandte Chemie International Edition, 51 (42). pp. 10643-10646. ISSN 1521-3773

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Abstract

The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air-stable AuII product, [(C N C)*2Au2], with a short nonbridged gold–gold bond.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Computing Sciences Faculty of Science > School of Chemistry
Depositing User:	Users 2731 not found.
Date Deposited:	21 Jan 2013 15:58
Last Modified:	08 Nov 2022 09:31
URI:	https://ueaeprints.uea.ac.uk/id/eprint/40899
DOI:	10.1002/anie.201206468

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