A thermally stable gold(III) hydride: Synthesis, reactivity, and reductive condensation as a route to gold(II) complexes

Roşca, Dragoş-Adrian, Smith, Dan A., Hughes, David L. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2012) A thermally stable gold(III) hydride: Synthesis, reactivity, and reductive condensation as a route to gold(II) complexes. Angewandte Chemie International Edition, 51 (42). pp. 10643-10646. ISSN 1521-3773

Full text not available from this repository. (Request a copy)

Abstract

The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air-stable AuII product, [(C N C)*2Au2], with a short nonbridged gold–gold bond.

Item Type: Article
Faculty \ School: Faculty of Science > School of Computing Sciences
Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Smart Emerging Technologies
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Faculty of Science > Research Groups > Chemistry of Light and Energy
Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User: Users 2731 not found.
Date Deposited: 21 Jan 2013 15:58
Last Modified: 08 Nov 2022 09:31
URI: https://ueaeprints.uea.ac.uk/id/eprint/40899
DOI: 10.1002/anie.201206468

Actions (login required)

View Item View Item