Roşca, Dragoş-Adrian, Smith, Dan A., Hughes, David L. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2012) A thermally stable gold(III) hydride: Synthesis, reactivity, and reductive condensation as a route to gold(II) complexes. Angewandte Chemie-International Edition, 51 (42). pp. 10643-10646. ISSN 1521-3773
Full text not available from this repository. (Request a copy)Abstract
The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air-stable AuII product, [(C N C)*2Au2], with a short nonbridged gold–gold bond.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Computing Sciences Faculty of Science > School of Chemistry |
UEA Research Groups: | Faculty of Science > Research Groups > Smart Emerging Technologies Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) |
Depositing User: | Users 2731 not found. |
Date Deposited: | 21 Jan 2013 15:58 |
Last Modified: | 31 Mar 2024 00:46 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/40899 |
DOI: | 10.1002/anie.201206468 |
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