N-heterocyclic pincer dicarbene complexes of iron(II): C-2 and C-5 metalated carbenes on the same metal center

Danopoulos, Andreas A., Tsoureas, Nikolaos, Wright, Joseph A. ORCID: https://orcid.org/0000-0001-9603-1001 and Light, Mark E. (2004) N-heterocyclic pincer dicarbene complexes of iron(II): C-2 and C-5 metalated carbenes on the same metal center. Organometallics, 23 (2). pp. 166-168. ISSN 0276-7333

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Abstract

Six- and five-coordinate Fe(II) complexes with the pincer ligand 2,6-bis(imidazolylidene)pyridine (C−N−C), [(C−N−C)Fe(MeCN)3][BPh4]2 and [(C−N−C)FeBr2], respectively, were synthesized. Substitution of tmeda in [FeCl2(tmeda)]2 by C−N−C gave the six-coordinate {[Fe(C−N−C)(C−N−C*)][FeCl4]}, in which one of the pincer ligands is bound to the metal via the 2- and 5-imidazole carbons.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Faculty of Science > Research Groups > Chemistry of Light and Energy
Faculty of Science > Research Groups > Energy Materials Laboratory
Depositing User: Users 2731 not found.
Date Deposited: 17 Oct 2012 08:44
Last Modified: 17 Jan 2024 01:23
URI: https://ueaeprints.uea.ac.uk/id/eprint/39937
DOI: 10.1021/om0341911

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