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Danopoulos, Andreas A., Tsoureas, Nikolaos, Wright, Joseph A. 
ORCID: https://orcid.org/0000-0001-9603-1001 and Light, Mark E.
(2004)
N-heterocyclic pincer dicarbene complexes of iron(II): C-2 and C-5 metalated carbenes on the same metal center.
Organometallics, 23 (2).
pp. 166-168.
ISSN 0276-7333
Abstract
Six- and five-coordinate Fe(II) complexes with the pincer ligand 2,6-bis(imidazolylidene)pyridine (C−N−C), [(C−N−C)Fe(MeCN)3][BPh4]2 and [(C−N−C)FeBr2], respectively, were synthesized. Substitution of tmeda in [FeCl2(tmeda)]2 by C−N−C gave the six-coordinate {[Fe(C−N−C)(C−N−C*)][FeCl4]}, in which one of the pincer ligands is bound to the metal via the 2- and 5-imidazole carbons.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Energy Materials Laboratory |
| Depositing User: | Users 2731 not found. |
| Date Deposited: | 17 Oct 2012 08:44 |
| Last Modified: | 24 Sep 2024 10:03 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/39937 |
| DOI: | 10.1021/om0341911 |
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