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Wright, Joseph A. 
ORCID: https://orcid.org/0000-0001-9603-1001, Danopoulos, Andreas A., Motherwell, William B., Carroll, Robert J., Ellwood, Simon and Saßmannshausen, Jorg
(2006)
“Pincer” N-heterocyclic carbene complexes of rhodium functionalised with pyridyl and bipyridyl donors.
European Journal of Inorganic Chemistry, 2006 (23).
pp. 4857-4865.
ISSN 1099-0682
Abstract
The “pincer”-type carbene complexes Rh(C–N–C)Cl and Rh(C–N–N)Cl [C–N–C = 3,3′-diaryl-1,1′-pyridine-2,6-diylbis(imidazol-2-ylidene), C–N–N = 1-aryl-3-(2,2′-bipyridin-6-yl)imidazol-2-ylidene] have been prepared and characterised by spectroscopic and diffraction methods. They bind CO to give cationic complexes but are inert to H2. Both oxidatively add CH2Cl2 to give octahedral RhIII complexes. Theoretical calculations provide insight into the bonding of the Rh(C–N–C)Cl and Rh(C–N–N)Cl complexes.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Energy Materials Laboratory |
| Depositing User: | Users 2731 not found. |
| Date Deposited: | 16 Oct 2012 12:47 |
| Last Modified: | 31 May 2023 15:30 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/39920 |
| DOI: | 10.1002/ejic.200600559 |
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