The hafnium-mediated NH activation of an amido-borane

Jacobs, Elizabeth A., Fuller, Anna-Marie, Lancaster, Simon J. and Wright, Joseph A. ORCID: https://orcid.org/0000-0001-9603-1001 (2011) The hafnium-mediated NH activation of an amido-borane. Chemical Communications, 47 (20). pp. 5870-5872. ISSN 1359-7345

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Abstract

Treatment of Cp2HfCl2 with two equivalents of LiNH2BH(C6F5)2 in toluene solution yields Cp2Hf{NHBH(C6F5)2}, which has been crystallographically characterised. The otherwise base-free [NHBH(C6F5)2] complex is stabilised by an agostic interaction.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Faculty of Science > Research Groups > Energy Materials Laboratory
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Faculty of Science > Research Groups > Chemistry of Light and Energy
Depositing User: Users 2731 not found.
Date Deposited: 21 Mar 2012 13:51
Last Modified: 15 Dec 2022 01:24
URI: https://ueaeprints.uea.ac.uk/id/eprint/38397
DOI: 10.1039/c1cc11320h

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