The hafnium-mediated NH activation of an amido-borane

Jacobs, Elizabeth A., Fuller, Anna-Marie, Lancaster, Simon J. and Wright, Joseph A. (2011) The hafnium-mediated NH activation of an amido-borane. Chemical Communications, 47 (20). pp. 5870-5872. ISSN 1359-7345

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Abstract

Treatment of Cp2HfCl2 with two equivalents of LiNH2BH(C6F5)2 in toluene solution yields Cp2Hf{NHBH(C6F5)2}, which has been crystallographically characterised. The otherwise base-free [NHBH(C6F5)2] complex is stabilised by an agostic interaction.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Energy Materials Laboratory Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy
Depositing User:	Users 2731 not found.
Date Deposited:	21 Mar 2012 13:51
Last Modified:	06 Feb 2025 01:46
URI:	https://ueaeprints.uea.ac.uk/id/eprint/38397
DOI:	10.1039/c1cc11320h

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