A C-2-symmetric metallocene-pyrrolidinopyridine nucleophilic catalyst for asymmetric synthesis

Nguyen, H. V., Motevalli, M. and Richards, C. J. ORCID: https://orcid.org/0000-0001-7899-4082 (2007) A C-2-symmetric metallocene-pyrrolidinopyridine nucleophilic catalyst for asymmetric synthesis. Synlett (5). pp. 725-728. ISSN 0936-5214

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Abstract

A C-2 -symmetric nucleophilic catalyst, (R,R)-3,5-diferrocenyl-4-(2',5'-dimethylpyrrolidino)pyridine, was synthesised in three steps from commercially available (S,S)-hexane-2,5-diol. Application to the kinetic resolution of secondary alcohols (0.5 mol% loading) resulted in selectivity factors (s) of up to 6.

Item Type:	Article
Additional Information:	Nguyen, Huy V. Motevalli, Majid Richards, Christopher J.
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	21 Feb 2012 10:46
Last Modified:	24 Sep 2024 09:42
URI:	https://ueaeprints.uea.ac.uk/id/eprint/37282
DOI:	10.1055/s-2007-970764

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