Allylic Imidate Rearrangements Catalyzed by Planar Chiral Palladacycles

Nomura, Hiroshi and Richards, Christopher J. ORCID: (2010) Allylic Imidate Rearrangements Catalyzed by Planar Chiral Palladacycles. Chemistry - An Asian Journal, 5 (8). pp. 1726-1740. ISSN 1861-4728

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The discovery that palladacycles are efficient catalysts for the allylic imidate rearrangement has resulted in the successful application of several such complexes to this reaction based on planar chiral iron and cobalt containing metallocenes. These palladacycles enable the efficient and highly enantioselective synthesis of a wide variety of protected allylic amines, which are valuable building blocks for use in asymmetric synthesis.

Item Type: Article
Uncontrolled Keywords: allylic compounds,asymmetric catalysis,metallocenes,palladacycles,planar compounds
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Feb 2012 11:31
Last Modified: 23 Oct 2022 01:35
DOI: 10.1002/asia.201000131

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