Allylic imidate rearrangements catalyzed by planar chiral palladacycles

Nomura, Hiroshi and Richards, Christopher J. ORCID: https://orcid.org/0000-0001-7899-4082 (2010) Allylic imidate rearrangements catalyzed by planar chiral palladacycles. Chemistry - An Asian Journal, 5 (8). pp. 1726-1740. ISSN 1861-4728

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Abstract

The discovery that palladacycles are efficient catalysts for the allylic imidate rearrangement has resulted in the successful application of several such complexes to this reaction based on planar chiral iron and cobalt containing metallocenes. These palladacycles enable the efficient and highly enantioselective synthesis of a wide variety of protected allylic amines, which are valuable building blocks for use in asymmetric synthesis.

Item Type:	Article
Uncontrolled Keywords:	allylic compounds,asymmetric catalysis,metallocenes,palladacycles,planar compounds
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	21 Feb 2012 11:31
Last Modified:	24 Sep 2024 09:15
URI:	https://ueaeprints.uea.ac.uk/id/eprint/37272
DOI:	10.1002/asia.201000131

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